張興杰
張興杰
博士，副教授，河南省優(yōu)青，碩士生導師
E-mail: [email protected]
教育及工作經(jīng)歷：
2023.04 - 至今，河南師范大學，化學化工學院，副教授
2018.07 - 2023.04，河南師范大學，化學化工學院，講師
2013.09 - 2018.06，中國科學院大學，上海有機化學研究所，有機化學專業(yè)，理學博士（碩博連讀），導師：劉元紅 研究員
2009.09 - 2013.06，洛陽師范學院，化學化工學院，應用化學專業(yè)，理學學士
研究興趣和領域：
利用過渡金屬催化的策略，通過巧妙地設計和開發(fā)新型配體，發(fā)展新穎、高效的催化體系，解決有機合成中長期存在的難點和挑戰(zhàn)性問題，主要集中于：
1) 基于發(fā)展新試劑與新反應的合成方法學研究
2) 基于廉價過渡金屬如鎳、銅等催化的新型、綠色交叉偶聯(lián)反應研究
Publications：
(10) Zhang, X.;* Cui, S.; Wei, S.; Zhao, M.; Liu, X.;* Zhang, G.* Nickel-Catalyzed Deaminative Alkyl-Alkyl Cross-Coupling of Katritzky Salts with Cyclopropanols: Merging C-N and C-C Bond Activation. Org. Lett. 2024, doi:10.1021/acs.orglett.4c00424.
(9) Liu, X.; Jiao, C.; Cui, S.; Liu, Q.; Zhang, X.;* Zhang, G.* Recent Advances in Nickel-Catalyzed Synthesis of Allenes: New Insights and Perspectives. ChemCatChem 2023, 15, e202300601. (Invited Review)
(8) Qi, D.; Zhang, X.;* Wang, X.; Liu, X.; Zhang, Z.; Shi, L.; Zhang, G.* Nickel-Catalyzed Reductive Iminoarylation of Oxime Ester-Tethered Alkenes: Rapid Entrance to Diverse Functionalized Pyrrolines. Org. Lett. 2023, 25, 1126-1130. (Highlighted by Synfacts)
(7) Zhang, X.;* Wang, X.; Jiao, C.; Zhao, J.; Liu, X.; Zhang, Z.; Zhang, G.* Transition-metal-free, Mild and Efficient Ring Expansion of Amino Acid Derivatives: Facile Access to Densely Functionalized Azepines. Org. Chem. Front. 2022, 9, 5516-5522.
(6) Zhang, X.;* Jiao, C.; Qi, D.; Liu, X.; Zhang, Z.; Zhang, G.* Nickel-Catalyzed Deaminative Allenylation of Amino Acid Derivatives: Catalytic Activity Enhanced by an Amide-Type NN2 Pincer Ligand. Org. Lett. 2022, 24, 5361-5365. (Highlighted by CBG news and Organic Chemistry Portal)
(5) Zhang, X.;* Qi, D.; Jiao, C.; Zhang, Z.; Liu, X.; Zhang, G.* Ni-Catalyzed Direct Iminoalkynylation of Unactivated Olefins with Terminal Alkynes: Facile Access to Alkyne-Labelled Pyrrolines. Org. Chem. Front. 2021, 8, 6522-6529.
(4) Zhang, X.;* Qi, D.; Jiao, C.; Liu, X.; Zhang, G.* Nickel-Catalyzed Deaminative Sonogashira Coupling of Alkylpyridinium Salts Enabled by NN2 Pincer Ligand. Nat. Commun. 2021, 12, 4904. (Featured in Org. Chem. Highlights)
Prior to HNU (Henan Normal University)
(3) Zhang, X.; Xie, X.; Liu, Y.* Nickel-Catalyzed Highly Regioselective Hydrocyanation of Terminal Alkynes with Zn(CN)2 Using Water as the Hydrogen Source. J. Am. Chem. Soc. 2018, 140, 7385-7389.
(2) Zhang, X.; Xia, A.; Chen, H.; Liu, Y.* General and Mild Nickel-Catalyzed Cyanation of Aryl/Heteroaryl Chlorides with Zn(CN)2: Key Roles of DMAP. Org. Lett. 2017, 19, 2118-2121.
(1) Zhang, X.; Xie, X.; Liu, Y.* Nickel-Catalyzed Cyclization of Alkyne-Nitriles with Organoboronic Acids Involving anti-Carbometalation of Alkynes. Chem. Sci. 2016, 7, 5815-5820.
