曹厚繼
曹厚繼
博士，副教授（校聘），碩士生導(dǎo)師
E-mail: [email protected]
Office: N-417
ORCID: https://orcid.org/0000-0002-0539-9124
課題組主頁：http://www.boronchemistry.net
教育經(jīng)歷
2016.08-2021.09 南京大學(xué) 化學(xué)化工學(xué)院 化學(xué) 理學(xué)博士
2013.09-2016.07 河南師范大學(xué) 化學(xué)化工學(xué)院 無機化學(xué) 理學(xué)碩士
2009.09-2013.07 河南師范大學(xué) 化學(xué)與環(huán)境科學(xué)學(xué)院 化學(xué) 理學(xué)學(xué)士
工作經(jīng)歷
2022.02-至今 河南師范大學(xué) 化學(xué)化工學(xué)院 副教授（校聘）
研究領(lǐng)域與興趣
硼化學(xué)，金屬有機化學(xué)，功能導(dǎo)向的精準有機合成方法學(xué)，配位化學(xué)
科研項目
1. 國家自然科學(xué)基金青年項目：α-羰基亞砜葉立德參與的碳硼烷并硼雜環(huán)化合物的精準合成（22201067，2023.01-2025.12），主持
2. 河南師范大學(xué)博士啟動課題，校20230206，2023.01-2025.12，主持
3. 國家自然科學(xué)基金重大研究計劃：硼簇衍生物在硼中子捕獲療法抗癌中的應(yīng)用（91961104，2020.01-2022.12），參與
4. 國家自然科學(xué)基金國際（地區(qū)）合作與交流項目：硼簇功能化新方法及潛在應(yīng)用（21820102004，2019.01-2023.12），參與
論文
15. Hou-Ji Cao*, Jia-Xin Li, Jia-Hui Yan, Miao-Xin Liu, Qianyi Zhao, Jie Zhang, Ju Zhang* and Hong Yan*,Post-Coordination of Ru(II) Controlled Regioselective B(4)–H Acylmethylation of o-Carboranes with Sulfoxonium Ylides, Chem. Sci., 2025, 16, 9406-9412. (SCI一區(qū)Top, IF = 7.6)
14. Shengwen Xu, Hongjian Zhang, Jibo Zong, Hou-Ji Cao, Deshuang Tu*, Chang-sheng Lu and Hong Yan*, Taming Inert B–H Bond with Low Energy Light: A Near-Infrared Light-Induced Approach to Facile Carborane Cluster-Amino Acid Coupling, J. Am. Chem. Soc., 2025, 147, 12845-12857. (SCI一區(qū)Top, IF = 14.5)
13. Jia-Rui Chang, Hou-Ji Cao, Yan-Na Ma* and Xuenian Chen*, Palladium-Catalyzed Cross-Coupling Reactions of Carboranes with Alkenes via Selective B?H Bond Activation, Org. Lett., 2025, 27, 1858-1863. (SCI一區(qū)Top, IF = 4.9)
12. Qiao-Jing Pan, Yu-Qi Miao, Hou-Ji Cao, Zhenxing Liu* and Xuenian Chen*, Visible Light-Induced 1,2-Diphenyldisulfane-Mediated Defluoroborylation of Polyfluoroarenes, J. Org. Chem., 2024, 89, 5049-5059. (SCI二區(qū), IF = 3.4)
11. Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Chang-ShengLu, Deshuang Tu*, Jordi Poater, Miquel Solà* and Hong Yan*, Facile Construction of New Hybrid Conjugation via Boron Cage Extension, J. Am. Chem. Soc., 2023, 145, 3577-3587. (SCI一區(qū)Top, IF = 16.4)
10. Yingying Wang, Hui Han, Jia-Xin Kang, Jiamin Peng, Xiongxiong Lu, Hou-Ji Cao, Zhenxing Liu* and Xuenian Chen*, Silylium Ion-Mediated Cage-Opening Functionalization of Closo-B10H102? Salts, Chem. Commun., 2022, 58, 11933-11936. (SCI二區(qū)Top, IF = 6.1)
9. Bin Wang, Hongyuan Ren, Hou-Ji Cao*, Chang-ShengLu* and Hong Yan*, A Switchable Redox Annulation of 2-Nitroarylethanols Affording N-heterocycles: Photoexcited Nitro as a Multifunctional Handle. Chem. Sci., 2022, 13, 11074-11082. (SCI一區(qū)Top, IF = 9.97)
8. Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Jingkai Xu, Vladimir I. Bregadze, Deshuang Tu*, Chang-ShengLu* and Hong Yan*, Palladium-Catalyzed Hydroboration of Alkynes with Carboranes: Facile Construction of a Library of Boron Cluster-Based AIE-Active Luminogens, Angew. Chem. Int. Ed., 2022, 61, e202207125. (SCI一區(qū)Top, IF = 16.8)
7. Hou-Ji Cao, Xing Wei, Fangxiang Sun, Xiaolei Zhang*, Chang-ShengLu* and Hong Yan*, Metal-Catalyzed B–H Acylmethylation of Pyridylcarboranes: Access to Carborane-Fused Indoliziniums and Quinoliziniums, Chem. Sci., 2021, 12, 15563-15571. (SCI一區(qū)Top, IF = 9.8)
6. Hou-Ji Cao, Meng Chen, Fangxiang Sun, Yue Zhao, Chang-Sheng Lu, Xiaolei Zhang*, Zhuangzhi Shi* and Hong Yan*, Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B?H Poly-Arylation of Carborane, ACS Catal., 2021, 11, 14047-14057. (SCI一區(qū)Top, IF = 13.1)
5. Chun-Xiao. Li, Qian Ning, Wenxuan Zhao, Hou-Ji. Cao, Yi-Ping. Wang, Chang-ShengLu*, Yong Liang* and Hong Yan*, Rh‐Catalyzed Decarbonylative Cross‐Coupling Between o‐Carboranes and Twisted Amides: A Regioselective, Additive‐Free and Concise Late‐stage Carboranylation, Chem–Eur. J., 2021, 27, 2699-2706. (SCI二區(qū)Top, IF = 5.2)
4. Hou-Ji Cao, Huimin Dai, Xiaolei Zhang, Hong Yan* and Chang-Sheng Lu*, Synthesis and Characterization of Cp*Ir-Dithiolene-o-Carborane Phosphine Complexes: A Continuous Investigation of B?H?π Interaction, Mol. Phys., 2019, 117, 1287-1297. (SCI三區(qū), IF = 2.0)
3. Qianyi Zhao, Xin-Ting. Guan, Ting Dou, Hou-Ji. Cao, Na-Na Ma, Ting Xu, Peng-Hui. Gao, Xiao-Hua Kong, Jie Zhang, Xuenian Chen, Synthesis and Characterization of Bis(Pyrazolyl)Borate Ni(II) Complexes: Ligand Rearrangement and Transformation, Dalton Trans., 2019, 48, 13242-13247. (SCI二區(qū), IF = 4.2)
2. Chun-Xiao Li, Hao-Yun. Zhang, Tsz-Yung Wong, Hou-Ji Cao, Hong Yan* and Chang-Sheng. Lu*, Pyridyl-Directed Cp*Rh(III) Catalyzed B(3)?H Acyloxylation of o-Carborane, Org. Lett., 2017, 19, 5178-5181. (SCI一區(qū)Top, IF = 6.5)
1. Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang*, Lai-Sheng Wang*, Xuenian Chen*, Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(Pyrazolyl)Borate Copper Complexes, Dalton Trans., 2016, 45, 10194-10199. (SCI二區(qū), IF = 4.0)
學(xué)術(shù)會議
? 第2屆國際硼化學(xué)學(xué)術(shù)會議(ICBC-II)；太原；2019. 07.
? 第28屆國際金屬有機化學(xué)會議；佛羅倫薩；2018. 07.
? 第二十屆全國金屬有機化學(xué)學(xué)術(shù)討論會；南京；2018. 11.
? 中國化學(xué)會第十屆全國有機化學(xué)學(xué)術(shù)會議；深圳；2017. 12.
? 第16屆國際硼化學(xué)會議；香港；2017. 07.
