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姓名：何艷

職務：

職稱：副教授

電子郵箱：[email protected]

個人簡歷

何艷，副教授,，碩士生導師,。

教育/工作經歷

2020.05-至今      河南師范大學環(huán)境學院 副教授

2016.01-2020.04  河南師范大學環(huán)境學院 講師

2023.09-2024.09   廈門大學化學化工學院 訪問學者

2012.09-2015.12   河南師范大學環(huán)境學院 博士

2009.09-2012.07   河南師范大學化學化工學院 碩士

2005.09-2009.07   河南師范大學化學化工學院 學士

研究領域

1. 以綠色合成化學為導向的新反應方法和技術研究

2. 環(huán)胺類化合物的官能團化與骨架編輯的新策略研究

主要學術及社會兼職

Chemical Communications、Organic Chemistry Frontiers,、Organic Letters,、Journal of Organic Chemistry、Advanced Synthesis & Catalysis 期刊審稿人

科研項目情況

[1] 國家自然科學基金-青年項目,，21702050,，飽和環(huán)狀叔胺的C–N鍵氧化斷裂與重組及其在官能團化環(huán)胺衍生物合成中的應用，2018-2020,，25,，主持

[2] 河南省重點科技攻關項目，172102310590,，ddC/3TC-噻唑啉酮雜化體的綠色合成及抗HIV活性研究,，2017-2018，主持

[3] 河南省高?？萍紕?chuàng)新團隊支持計劃,，20IRTSTHN005，有機功能分子的綠色合成及性能研究,，2020-2021,，50萬，主要參與人

代表性論文

[1]Yan He,* Qimeng Liu, Jintao Yang, Yunfei Liu, Xinying Zhang, Xuesen Fan.* Oxoammonium salt-promoted diverse functionalization of saturated cyclic amines with dinucleophiles. Chem. Commun., 2023, 59,3874-3877.

[2]Yan He,* Qimeng Liu, Tian Gong, Yunfei Liu, Xinying Zhang, Xuesen Fan.* Tunable synthesis of α,β-multifunctionalized azaheterocycles via the cascade reaction of saturated cyclic amines with diverse nucleophiles promoted by oxoammonium salt. Org. Chem. Front., 2023, 10, 1206-1212.

[3]Yan He,* Qimeng Liu, Jintao Yang, Zhi Zheng, Guo-Li Chai, Xinying Zhang, Xuesen Fan.* Oxoammonium salt-promoted multifunctionalization of saturated cyclic amines based on β-oxo cyclic iminium ion intermediates. Org. Lett., 2022, 24, 7839-7844.

[4]Yan He,* Qimeng Liu, Zihe Du, Yanhua Xu, Lingyu Cao, Xinying Zhang, Xuesen Fan.* B(C₆F₅)₃-Catalyzed α,β-difunctionalization and C?N bond cleavage of saturated amines with benzo[c]isoxazoles: access to quinoline derivatives. J. Org. Chem., 2022, 87, 14840-14845.

[5]Yan He,* Zhi Zheng, Jintao Yang, Xinying Zhang, Xuesen Fan.* Recent advances in the functionalization of saturated cyclic amines. Org. Chem. Front., 2021, 8, 4582-4606.

[6] Yan He,* Jintao Yang, Xinying Zhang, Xuesen Fan.* Selective cleavage and reconstruction of C–N/C–C bonds in saturated cyclic amines: tunable synthesis of lactams and functionalized acyclic amines. Org. Chem. Front.,2021, 8, 5118-5123.

[7] Yan He,* Zhi Zheng, Qimeng Liu, Xinying Zhang, Xuesen Fan.* Solvent-regulated coupling of 2-alkynylbenzaldehydes with cyclic amines: selective synthesis of fused N-heterocycles and functionalized naphthalene derivatives. Org. Lett., 2020, 22, 9053-9058.

[8] Yan He,* Jintao Yang, Yajie Liu, Jiajie Qiao, Xinying Zhang, Xuesen Fan.* Synthesis of β-methyl sulfonylated N-heterocycles from saturated cyclic amines with the insertion of sulfur dioxide. J. Org. Chem., 2020, 85, 15600-15609.

[9] Yan He,* Zhi Zheng, Yajie Liu, Jiajie Qiao, Xinying Zhang, Xuesen Fan.* Selective synthesis of β-nitrated N-heterocycles and N-nitroso-2-alkoxyamine aldehydes from inactivated cyclic amines promoted by ^tBuONO and oxoammonium salt. Chem. Commun., 2019, 55,12372-12375.

[10] Yan He,* Zhi Zheng, Yajie Liu, Jiajie Qiao, Xinying Zhang, Xuesen Fan.* Selective cleavage and tunable functionalization of the C?C/C?N bonds of Narylpiperidines promoted by ^tBuONO. Org. Lett., 2019, 21,1676-1680.

[11] Yan He,* Tian Feng, Xuesen Fan.* Synthesis of functionalized indole-1-oxide derivatives via cascade reactions of allenynes and ^tBuONO. Org. Lett.,2019, 21, 3918-3922.

[12] Tian Feng, Yan He,* Xuesen Fan.* Synthesis of functionalized cyclobutane-fused naphthalene derivatives via cascade reactions of allenynes with tert-butyl nitrite. Adv. Synth. Catal., 2019, 361, 1271-1276.

[13] Fang Wang, Yan He,* Miaomiao Tian, Xinying Zhang, Xuesen Fan.* Synthesis of αformylated Nheterocycles and their 1,1-diacetates from inactivated cyclic amines involving an oxidative ring contraction. Org. Lett., 2018, 20, 864-867.

[14] Yan He,* Zhi Zheng, Qimeng Liu, Guixian Song, Nan Sun, Xinyuan Chai. Tunable synthesis of 2ene-1,4-diones, 4hydroxycyclopent-2-en-1-ones, and 2(furan-3-yl)acetamides via palladium-catalyzed cascade reactions of allenols.J. Org. Chem., 2018, 83, 12514-12526.

[15] Yan He,* Fang Wang, Xinying Zhang, Xuesen Fan.* C(sp³)–H dehydrogenation and C(sp²)–H alkoxycarbonylation of inactivated cyclic amines towards functionalized N-heterocycles. Chem. Commun., 2017, 53, 4002-4005.

[16] Yan He, Ningning Zhao, Liqi Qiu, Xinying Zhang,* Xuesen Fan.* Regio- and Chemoselective mono- and bisnitration of 8amino quinoline amides with Fe(NO₃)₃·9H₂O as promoter and nitro source. Org. Lett., 2016, 18,6054-6057.

[17] Yan He, Xinying Zhang*, and Xuesen Fan*. Synthesis of diversely substituted 2-(furan-3-yl)acetates from allenols through cascade carbonylations. Chem. Commun., 2015, 51, 16263-16266.

[18] Yan He, Xinying Zhang*, and Xuesen Fan*. One-pot cascade reactions of 1-arylpenta-3,4-dien-2-ones leading to 2-arylphenols and dibenzopyroanones. Chem. Commun., 2014, 50, 14968-14970.

[19] Yan He, Xinying Zhang and Xuesen Fan*. Synthesis of naphthalene amino esters and arylnaphthalene lactone lignans through tandem reactions of 2-alkynylbenzonitriles. Chem. Commun., 2014, 50, 5641-5643.

[20] Yan He, Shenghai Guo, Xinying Zhang, and Xuesen Fan*. Zinc-mediated one-pot tandem reaction of nitriles with propargyl bromides: an easy access to 3-alkynylpyri dines and their applications. J. Org. Chem., 2014, 79, 10611.

[21] Xuesen Fan*, Yan He, Xinying Zhang, Jianji Wang. Sustainable and selective synthesis of 3,4-dihydro quinolizin-2-one and quinolizin-2-one derivatives via the reactions of penta-3,4-dien-2-ones. Green Chem., 2014, 16, 1393-1398.

[22] Yan He, Xinying Zhang*, Liangyan Cui, Jianji wang, and Xuesen Fan*. Catalyst-free synthesis of diversely substituted 6H-benzo[c]chromenes and 6H-benzo[c]-chromen-6-ones in aqueous media under MWI. Green Chem., 2012, 14, 3429-3435.

　授權發(fā)明專利

[1] 何艷,，崔嘯,，牛佳文，張志遠,，范學森,，張新迎,，一種α-取代-β-胺氧基取代嗎啉類化合物的合成方法，2024-09-06,，中國,，ZL202211339826.1.

[2]何艷，杜子翯,，劉奇夢,，范學森，張新迎,，一種3-取代喹啉類化合物的合成方法,，2024-1-26，中國,，ZL202210965357.8.

[3]何艷,，杜子翯，馬靖涵,，徐艷華,，張新迎，范學森,，一種N-芳基取代內酰胺類化合物的合成方法,，2023-8-29，中國,，ZL202110641292.7.

[4]何艷,，張新迎，范學森,，楊錦濤,，一種3-甲磺酰基取代氮雜環(huán)類化合物的合成方法,，2022-2-25，中國,，ZL202011174018.5.

[5] 何艷,，范學森，鄭智,，張新迎,，一種多取代萘并氮雜環(huán)類化合物的合成方法，2022-2-8,，中國,，ZL202010931477.7.

[6] 何艷，范學森,，張新迎,，鄭智,，一種N-亞硝基-2-烷氨氧基醛類化合物的合成方法，2021-6-4,，中國,，ZL201910864065.3.

[7] 何艷，張新迎,，王芳,，范學森，一種α-二乙酰氧甲基取代含氮雜環(huán)類化合成方法,，2020-1-31,，中國，ZL201710903936.9.

[8] 何艷,，范學森,，張新迎，趙寧寧,，邱麗琪,，一種5-硝基-8-酰胺基喹啉類化合物的合成方法，2019-1-1,，中國,，ZL201610926193.2.