張絜

博士,，研究員,，博士生導(dǎo)師,，河南師范大學(xué)特聘教授

Email:   [email protected]

教育經(jīng)歷:

博士, 中國(guó)科學(xué)院蘭州化學(xué)物理研究所,，1999

碩士, 中國(guó)科學(xué)院青海鹽湖研究所,，1996

科研經(jīng)歷：

2013/09—          河南師范大學(xué),，化學(xué)化工學(xué)院,，研究員,，特聘教授

2010/11—2013/08,，美國(guó)俄亥俄國(guó)家生化試劑公司,，研究員，研發(fā)部主任

2004/04—2010/10,，美國(guó)布魯克黑文國(guó)家實(shí)驗(yàn)室,，辛辛那提大學(xué)，研究員

2001/06—2004/03,，英國(guó)諾丁漢大學(xué),，化學(xué)系，研究員

1999/08—2001/06，中國(guó)科學(xué)院化學(xué)研究所,，博士后

主講課程：

高等無(wú)機(jī)化學(xué), 無(wú)機(jī)化學(xué)前沿

研究領(lǐng)域與興趣：

金屬有機(jī)合成化學(xué),，硼化學(xué)，均相催化反應(yīng)機(jī)理

近年來(lái)主持的主要科研項(xiàng)目：

國(guó)家自然科學(xué)基金資助項(xiàng)目(2016.01-2019.12)：“新型硼氮空間受阻路易斯酸堿對(duì)的合成及其在催化還原二氧化碳中的應(yīng)用”, 批準(zhǔn)號(hào)：21571052.

河南省重點(diǎn)科技攻關(guān)項(xiàng)目(2015.01-2016.12)：“新型硼氮空間受阻路易斯酸堿對(duì)的合成與催化性能研究”, 批準(zhǔn)號(hào)：152102210085.

近期代表性論文：

1.  Jiarui Chang, Fei Fang, Jie Zhang*, Xuenian Chen*,  “Hydrosilylation of Aldehydes and Ketones Catalysed by Bis(phosphinite) Pincer Platinum Hydride Complexes”, Adv. Synth. Catal. 2020, 362, 2709–2715.

2.  Yan-Na Ma, Yan Gao, Yi Jing, Jiaxin Kang, Jie Zhang*, Xuenian Chen*, “Syntheses of Bromo?N?heterocycles through DibromohydantoinPromoted Tandem C?H Amination/Bromination”, J. Org. Chem. 2020, 85, 2918–2926.

3.  Bula Cao, Yazhou Ding, Fei Fang, Jiarui Chang, Jie Zhang*, Shujun Li, Xuenian Chen*, “The stability of group 10 metal POCOP pincer complexes: decomposition/reconstruction pathways of the pincer backbone”, Dalton Trans. 2019, 48, 13760–13768.

4.  Yazhou Ding, Qiang-Qiang Ma, Jiaxin Kang, Jie Zhang*, Shujun Li, Xuenian Chen*, Palladium(II) complexes supported by PBP and POCOP pincer ligands: a comparison of their structure, properties and catalytic activity, Dalton Trans. 2019, 48, 17633–17643.

5.  Xi-Meng Chen, Jin Wang, Si-Cong Liu, Jie Zhang*, Donghui Wei*, Xuenian Chen*, “Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH₃BH₃ with NaH and the mechanistic study”, Dalton Trans. 2019, 48, 14984–14988.

6.  Yan-Na Ma, Yajing Bian, Xin Liu, Jie Zhang*, Xuenian Chen*, “One-Pot Synthesis of Iodo-Dibenzothiazines from 2?Biaryl Sul?des”, J. Org. Chem. 2019, 84, 450?457. 

7.  Shujun Li, Yue Zhao, Huihui Qi, Yanfang Zhou, Shuxia Liu, Xiaoming Ma, Jie Zhang*, Xuenian Chen*, “Boronic acid derivatized lanthanide–polyoxometalates with novel B–OH–Ln and B–O–Nb bridges”,  Chem. Commun. 2019, 55, 2525?2528.

8.      Jie Zhang*, Ting Liu, Qiang-Qiang Ma, Shujun Li, Xuenian Chen*, “A reaction of [2,6-(^tBu₂PO)₂C₆H₃]NiSCH₂Ph with BH₃·THF: borane mediated C–S bond cleavage”, Dalton Trans. 2018, 47, 6018–6024.

9.      Jie Zhang*, Ting Liu, Changgeng Wei, Jiarui Chang, Qiang-Qiang Ma, Shujun Li, Nana Ma*, Xuenian Chen*, “The Reactivity of Mercapto Groups against Boron Hydrides in Pincer Ligated Nickel Mercapto Complexes”, Chem. Asian J. 2018, 13, 3231–3238.

10.  Yan-Na Ma, Chen-Yang Guo, Qianyi Zhao, Jie Zhang*, Xuenian Chen*, “Synthesis of dibenzothiazines from sul?des by one-pot N,O-transfer and intramolecular C–H amination”,  Green Chem. 2018, 20, 2953–2958.

11.  Xi-Meng Chen, Nana Ma, Qian-Fan Zhang, Jin Wang, Xiaoge Feng, Changgeng Wei, Lai-Sheng Wang*, Jie Zhang*, Xuenian Chen*, “Elucidation of the Formation Mechanisms of the Octahydrotriborate Anion (B₃H₈^?) through the Nucleophilicity of the B?H Bond” J. Am. Chem. Soc. 2018, 140, 6718?6726.

12.  Ting Liu, Wenjuan Meng, Qiang-Qiang Ma, Jie Zhang*, Huizhen Li, Shujun Li, Qianyi Zhao, Xuenian Chen*, “Hydroboration of CO₂ Catalyzed by Bis(phosphinite) Pincer Ligated Nickel Thiolate Complexes”, Dalton Trans. 2017, 46, 4504?4509.

13.  Qiang-Qiang Ma, Ting Liu, Anubendu Adhikary, Jie Zhang*, Jeanette A. Krause, Hairong Guan*, “Using CS₂ to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes”, Organometallics 2016, 35, 4077?4082.

14.  Qiang-Qiang Ma, Ting Liu, Shujun Li, Jie Zhang*, Xuenian Chen*, Hairong Guan*, “Highly Efficient Reduction of Carbon Dioxide with a Borane Catalyzed by Bis(phosphinite) Pincer Ligated Palladium Thiolate Complexes”, Chem. Commun. 2016, 52, 14262?14265.

15.  Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang*, Lai-Sheng Wang*, Xuenian Chen*, “Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(pyrazolyl)borate Copper Complexes”, Dalton Trans. 2016, 45, 10194?10199.

16.  Huizhen Li, Nana Ma, Wenjuan Meng, Judith Gallucci, Yongqing Qiu, Shujun Li, Qianyi Zhao, Jie Zhang*, Ji-Cheng Zhao*, Xuenian Chen*, “Formation Mechanisms, Structure, Solution Behavior and Reactivity of Aminodiborane”, J. Am. Chem. Soc. 2015, 137, 12406?12414.